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TRIMETHYLGALLIUM
Base Information
- Chemical Name:TRIMETHYLGALLIUM
- CAS No.:1445-79-0
Cost-effective customized wholesale TRIMETHYLGALLIUM 1445-79-0
- Molecular Formula:C3H9Ga
- Molecular Weight:114.827
- Appearance/Colour:COA
- Melting Point:-15.8 °C
- Boiling Point:55.7 °C
- Flash Point:-18 °C
- PSA：0.00000
- Density:1.151 g/cm3
- LogP:1.37060
TRIMETHYLGALLIUM(Cas 1445-79-0) Usage
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Chemical Description |
Trimethylgallium is an organometallic compound with the chemical formula Ga(CH3)3. |
InChI:InChI=1/3CH3.Ga/h3*1H3;/rC3H9Ga/c1-4(2)3/h1-3H3
1445-79-0 Relevant articles
The Synthesis and Properties of Dimethylgallane: Structure of the Dimer Me2Ga(μ-H)2GaMe2 in the Gas Phase as determined by Electron Diffraction
Baxter, Paul L.,Downs, Anthony J.,Goode, Michael J.,Rankin, David W. H.,Robertson, Heather E.
, p. 805 - 806 (1986)
Dimethylgallane, best synthesised by the...
"Metastable" Lu(GaMe4)3 reacts like masked [LuMe3]: Synthesis of an unsolvated lanthanide dimethyl complex
Zimmermann, Melanie,Litlabo, Rannveig,Toernroos, Karl W.,Anwander, Reiner
, p. 6646 - 6649 (2009)
Homoleptic tetramethylgallate Lu(GaMe4)3...
Coordination complexes derived from 3,6-di(2-pyridyl)-1,4-dihydro-1,2,4,5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2)2]
Preston, Peter N.,Rettig, Steven J.,Storr, Alan,Trotter, James
, p. 1800 - 1804 (1998)
The facile reaction of 3,6-di(2-pyridyl)...
Aryl-NHC-group 13 trimethyl complexes: structural, stability and bonding insights
Wu, Melissa M.,Gill, Arran M.,Yunpeng, Lu,Yongxin, Li,Ganguly, Rakesh,Falivene, Laura,García, Felipe
, p. 854 - 864 (2017)
Treatment of aromatic N-substituted N-he...
Homoleptic and heteroleptic gallium(III) compounds containing monosubstituted cyclopentadienyl ligands: Ga(C5H4Me)3, Ga(C5H4SiMe3)3, and R2Ga(C5H4
Beachley Jr.,Mosscrop, Michael T.
, p. 4550 - 4556 (2000)
The new gallium(III) cyclopentadienyl de...
Reactivity of carbonyl-functionalized phosphaalkenes RC(O)P=C(NMe2)2 (R = tBu, ph) towards electrophiles
Weber, Lothar,Uthmann, Stefan,Stammler, Hans-Georg,Neumann, Beate,Schoeller, Wolfgang W.,Boese, Roland,Bl?ser, Dieter
, p. 2369 - 2381 (1999)
The reaction of the carbonyl-functionali...
A new synthetic route to trimethylgallium
Revin,Artemov,Sazonova
, p. 1359 - 1363 (2013)
A new synthetic route to trimethylgalliu...
Polymorphism in the crystal structures of the group 13 trimethyls
Boese, Roland,Downs, Anthony J.,Greene, Timothy M.,Hall, Alexander W.,Morrison, Carole A.,Parsons, Simon
, p. 2450 - 2457 (2003)
Crystal structure have been determined f...
71Ga NMR studies of mixtures of gallium trichloride and trimethylgallium
Cerny, Z.,Machacek, J.,Fusek, J.,Kriz, O.,Casensky, B.,Tuck, Dennis G.
, p. 25 - 30 (1993)
71Ga NMR spectra of solutions of GaCl3 a...
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Kraus,Toonder
, p. 292 (1933)
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Process for preparing alkyl metal compounds
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Paragraph 0122-0125, (2020/05/30)
The invention relates to a method for pr...
PROCESS FOR PURIFICATION OF DIMETHYL ALUMINIUM CHLORIDE
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Page/Page column 7, (2019/07/19)
Process for the removal of gallium compo...
METHOD FOR STORING AND/OR TRANSPORTING GALLIUM CHLORIDE
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Page/Page column 8, (2019/05/22)
Method for storing and/or transporting G...
PROCESS FOR THE PREPARATION OF TRIMETHYL METAL COMPOUNDS
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Page/Page column 7-8, (2017/03/21)
Process for the preparation of a trimeth...
1445-79-0 Process route
-
-
7440-55-3
gallium
-
-
7439-95-4
magnesium
-
-
74-88-4
methyl iodide
-
-
7786-30-3
magnesium chloride
-
-
1445-79-0
trimethyl gallium
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
inert gas atmosphere; mixing, heating in autoclave (100 - 160°C, stirring, 12 h); distillation;
|
65% |
-
-
trimethyl gallium ; compound with trimethylarsine
-
-
593-88-4
trimethylarsine
-
-
1445-79-0
trimethyl gallium
| Conditions | Yield |
|---|---|
|
In
gas;
dissociation above 450 K;
Kinetics;
|
1445-79-0 Upstream products
-
544-97-8
dimethyl zinc(II)
-
593-74-8
dimethylmercury
-
75-24-1
trimethylaluminum
-
1184-58-3
dimethylaluminum chloride
1445-79-0 Downstream products
-
7440-55-3
gallium
-
99601-83-9
monomethyl gallium
-
106693-86-1
dimethylgallium
-
13450-90-3
Gallium trichloride
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